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Responding to her, state Health Minister C Vijayabaskar said an ordinance in this regard would be submitted to the Centre tomorrow morning.
The development comes after Tamil Nadu Chief Minister K Palaniswami, state ministers and Lok Sabha Deputy Speaker M Thambidurai had multiple meetings with Prime Minister Narendra Modi and other Central ministers over NEET.
Tamil Nadu, which had initially sought permanent exemption from NEET by passing two Bills in the Assembly, later made efforts to be out of its ambit for at least a year or two.
Barring government colleges, NEET was already implemented for other institutes, the Union minister said.
In Puducherry, Union Minister Pon Radhakrishnan said the Centre was inclined to accept the representation from Tamil Nadu on NEET.
Terming Sitharaman's remarks a "good news" Vijayabaskar said, "I thank Union Minister Nirmala Sitharaman and Prime Minister Narendra Modi on behalf of Tamil Nadu government and students."
Tomorrow morning the state ordinance seeking exemption from NEET would be submitted to the Centre. A government secretary would be leaving for Delhi tonight and the ordinance would be promulgated after consultations with the chief minister, he said.
The state health minister said the Tamil Nadu government was confident of the Centre's nod for the ordinance and under no circumstances had the Centre been "negative" about the proposal.
"We are seeking exemption only for seats in government colleges and government quota seats in self-financing colleges," he said, adding it was not sought for private institutes.
Vijayabaskar said care is being taken to ensure that the proposed move does not face any legal hurdles and the government was confident of completing the admission process ahead of the month-end deadline.
In future, students would be well-prepared for NEET and the syllabus too would be oriented likewise, he said.
He said if the BJP-led government at the Centre was truly interested in the welfare of Tamil Nadu students it should get Presidential assent for the two Bills for permanent exemption of the state from NEET.
Actor Kamal Haasan meanwhile, in a tweet, asked the state government to "talk immediately" (with the Centre) on the NEET issue since the matter involved the future of students.