Jolie spotted smoking after 'fuming row' with hubby Brad Pitt

Angelina Jolie was spotted smoking a cigarette after a heated argument with husband Brad Pitt at a Sydney hotel.

According to an eyewitness, the couple, who was in Australia for the premiere of the 39-year-old actress' new film 'Unbroken,' looked frustrated with Pitt throwing his arms up and down during the verbal spat on a balcony at the Intercontinental Sydney hotel, News.com.au reported.

Jolie, who had recently undergone a double mastectomy as a preventative measure against cancer, looked near tears, and the row ended with Pitt walking away leaving the 'Maleficent' star to finish her cigarette.

Later, they both headed to the film's premiere, where they seemed distant with each other, and once they were finished, both went their separate ways.