The meeting today afternoon started breaking up after less than an hour, with the ambassadors of China, France, Britain, Russia and the United States steadily walking out.
It was the second time in two days that the five Security Council powers came out of a meeting on Syria with no progress.
Yesterday, the five countries met to discuss a resolution proposed by Britain to authorise the use of military force against Syria in retaliation for an alleged chemical weapons attack that killed hundreds near Damascus.
British Ambassador Mark Lyall Grant looked grim as he walk past reporters today, saying "no comment." The other ambassadors also did not speak to reporters.
A Western diplomat, who spoke on condition of anonymity because the talks were private, said Russia called today's meeting. Russia's UN mission refused to comment.
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