Logging nine points from four matches, Argentina stayed ahead of Olympic champions Germany, who are in danger of failing to make the semifinals only for the second time in World Cup history.
Peillat converted two early penalty corners to give Argentina a two-goal lead by the seventh minute. Lucas Vila then scored a field goal, before Peillat returned for his third goal in the 20th minute that gave the Argentines a 4-0 lead at half-time.
Until now, it was only in the first World Cup in 1971 that Germany did not feature in the semifinals.
The Netherlands have nine points from three successive wins and will play South Africa later tonight. Even a draw will take three-time World Cup winners The Netherlands to the semifinals.
Zellar could have added another goal, but missed a penalty stroke.
Andy Hayward scored a hat-trick for New Zealand with his last two goals coming in the last four minutes of the match.
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