The 41-year-old actress, who confirmed her separation in April, share two young daughters, Olive and Frankie, with Kopelman, reported People magazine.
Following their split, Barrymore and the art consultant insisted that despite calling it quits, their family would stay intact.
Their statement added that their girls will remain the first priority for "the rest of our lives."
The "50 First Dates" star and Kopelman, 39, started dating in 2011 after years of friendship, and tied the knot in 2012.
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