Clifford Lee, 53, of St Louis, died yesterday at St Louis University Hospital, the medical examiner said.
Lee was with two friends Monday filling out new employee paperwork at Faultless Linen Co when the one-ton boiler exploded at nearby Loy-Lange Box Co flew through the air and crashed through the linen company's roof, The St Louis Post-Dispatch reported.
His friends, Christopher Watkins, 46, and Tonya Suarez-Gonzalez, 43, a married couple from St. Ann, Missouri, died at the scene.
Investigators from the US Department of Labor's Occupational Safety and Health Administration and local authorities are investigating the cause of the explosion. St Louis Fire Chief Dennis Jenkerson has said he believes the explosion was a commercial accident.
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