"We have arrested more than 200 looters since last night," national police chief Jean-Thierry Oye Zue told AFP. "Looting is currently continuing in the poorer districts."
"Six police officers have been injured," Oye Zue said, adding that several civilians had also "most likely" been hurt.
He did not confirm however there had been any deaths.
"I can't tell you that," he said.
AFP journalists saw two trucks packed with dozens of detainees, who raised their fists in the air and chanted the Central African country's national anthem as they were driven off for questioning.
The opposition leader said security forces killed two people and injured 19 more at his headquarters.
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