Hindalco's scrip dipped 4 per cent to Rs 74.20 on BSE and Vedanta fell by 3 per cent to Rs 90.35.
Both the scrips were the worst performers on the 30-share benchmark index.
These stocks would be replaced by Adani Ports and Special Economic Zone and Asian Paints Ltd.
Adani Ports' scrip gained 3.42 per cent to Rs 279.
Similarly, shares of Asian Paints rose by 2.67 per cent to Rs 849.
The Sensex was trading 23.38 points lower at 25,845.11.
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