The new "de facto authorities" in Kiev threaten Ukraine's unity, stability in the region and Russia's sovereignty, Maduro's office said in a statement.
Maduro, it said, "rejects the coup d'etat perpetrated by extremist groups in Ukraine, after a strategy of erosion promoted from outside by the US government and its NATO allies."
Ukrainian president Viktor Yanukovych was ousted last month after a deadly crackdown on protesters angry at his decision to ditch a pact with the European Union in favour of closer ties with Moscow.
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