She also shared a text from her publicist that said there are reports she is dating Theroux, to which she responded, "Oh my god. That is so stupid."
"Dear tabloids, please stop matching me with my friends' exes. No disrespect to people who do date their friends' exes, that's just not my style," she wrote in another Instagram Story.
Munn has appeared in films with both Aniston and Theroux, who announced their decision to separate after two years of marriage on February 15.
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