The woman, Komal Goyani, is the sister of main accused Gautam aka Golden Goyani, whose father, too, is wanted in the case, they said.
"We arrested Komal from her house at Kamrej near here late on Sunday night and are looking out for four others, including the main accused Golden," Varachha Police Inspector C K Patel said.
Police had yesterday arrested Mehul Bharwad, Lalu Bharwad and Imran in the case.
"Komal dabbled in politics and had contested taluka-level election from Kamrej in Surat district on Congress ticket but was defeated. She was involved in settling land disputes and had recently helped Balu in clearing a land deal," Patel said.
The other absconding accused are Kishan Khokhar, Bhadresh Patodiya and Golden's father Ganesh. The car and weapons used in the murders have not been recovered yet, police said.
Patel said Balu came in contact with Komal through her father Ganesh.
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