The 34-year-old "Quantico" actress teamed the outfit with a statement neck piece.
Priyanka, who normally opts for a clean hairdo, took a chance by leaving her hair open. She, however, stuck to her trademark bold lips.
"Collection gold, one-of-a-kind hand-embroidered evening dress. #GoldenGlobes," read a post on Ralph Lauren's official Twitter page.
The actress took to stage along with Jeffrey Dean Morgan at the Golden Globes to present an award to Billy Bob Thornton.
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