Putin said the Russian move announced earlier this week had been prompted by "restrictions and provocations" by Ukrainian authorities that made it hard for Russian officers to perform their duties.
Ukraine has criticised Moscow's decision, saying it could fuel hostilities.
The Kremlin said Putin and Merkel agreed Thursday to consider possible steps to ensure the Russian monitors' return. It added that they also spoke in support of a planned prisoners' exchange and a truce for the holiday season.
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