Govindan, wanted in several criminal cases, attacked two police constables, who were on patrol duty last night, with a sickle, while he was trying to flee after snatching a gold chain from a woman, they said.
However, Soundarapandi and Thangamunisamy opened fire thrice at Govindan "in self-defence," killing him on the spot, they added.
The injured policemen have been admitted to Ramanathapuram government hospital, where they are said to be in a serious condition, police said.
Superintendent of police, Mayilvahanan rushed to the spot and held investigations.
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