The fourth seeded Indo-Zimbabwean pair lost 3-6 3-6 in round two of the USD 2,567,000 hard court event in the run up to the US Open, the last Grand Slam tournament of the season.
Sania and Cara had got a bye in the first round.
Earlier, fifth seeds Leander Paes and Radek Stepanek were eliminated from the ATP Cincinnati Masters after their defeat against Vasek Pospisil and Jack Sock in the second round.
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