The shoplifter in yesterday's Home Depot incident was not injured, the Detroit Free Press said.
It was not clear if the woman, who has a license to carry a concealed weapon, would face any charges for taking the law into her own hands.
The woman, 48, was in the parking lot when she saw a security guard chase a black man in his 40s out of the store. The man jumped into a waiting sports utility vehicle and the woman opened fire when it began to pull away. Police believe she shot out one of the tires.
It noted that "business was not disrupted" and asked for the public's help in locating the "getaway" car.
The incident comes just a few weeks after a bank customer in a neighboring Detroit suburb shot a robber as he was fleeing the scene.
The local mayor said the 63-year-old man, who also had a license to carry a weapon, acted within his rights because the robber threatened him on his way out the door.
The robber, 43, was treated in hospital after being shot once in each arm and once in a leg.
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