The youth (21), identified only as Pradeep, entered the premises of the college of the girl, a first-year student of engineering, posing as a student in college uniform and slashed her, they said.
Pradeep was pursuing a technical course at another institute.
The girl sustained serious injuries on her head and left hand, a senior police officer said, adding that she and Pradeep were immediately rushed to separate private hospitals.
The college authorities have handed over the CCTV footage of the incident to police, he said.
"The girl was known to Pradeep for the last four years. For the past two years, he had been pestering her with love proposals besides harassing her to marry him, which she rejected. He even teased her on several occasions," the ACP told PTI.
"After the relations between them strained, the girl had recently lodged a complaint with police alleging that her boyfriend had outraged her modesty and since then Pradeep had been absconding," the ACP said.
Chandrayangutta police are conducting further probe in the case.
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