The toll was one of the highest reported since the signing of the September 5 truce agreement, and brings the number of civilians killed in sporadic mortar and rocket attacks to 14 since the weekend.
The civilians were killed in both the eastern rebel-run territories of Lugansk and Donetsk, local officials said.
The Ukrainian military said its soldiers were also killed across the industrial Russian-border region.
"As a result of shelling and clashes in various areas where the anti-terrorist operation is being waged, five Ukrainian servicemen died," National Security and Defence Council spokesman Andriy Lysenko told reporters.
The rebels do not report their own losses and Ukraine's daily claims of heavy casualties in their ranks have been impossible to confirm.
The latest casualties bring to 100 the number of Ukrainian soldiers and civilians reported killed since the truce agreement, which was backed by Russia and European envoys.
Insurgency leaders signed up to the peace pact but soon accused Kiev of breaking the ceasefire. Some have since vowed to keep fighting until all Ukrainian forces pull out of their self-proclaimed states.
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