The Indian hockey eves, ranked 13 in the world, prevailed 5-4 over world rank 16 Italy in the shoot-out of the first play-off match for the fifth to eighth positions, after both the teams were locked at 1-1 at the end of the regulation 60 minutes.
India failed to capitalise on numerous opportunities during the regulation time. The ensuing shoot-out also failed to break the deadlock as both the teams scored four times each from their five shots and the contest went to sudden-death.
Rani Rampal had earlier scored the equaliser for India in the 33rd minute after Italy opened the scoring against the run of play in the ninth minute of the contest.
In the shoot-out, experienced striker Vandana Katariya muffed her attempt while Navjot Kaur, Anuradha Thokchom, Rani Rampal and Deepika scored for India. For Italy, Valentina Braconi, Marcela Casale, Guiliana Ruggieri and Chiara Tiddi shot on target but Dalila Mirabella was denied by the Indian custodian.
Three Olympic spots are on offer in this tournament, but even some teams not advancing to the semifinals are likely to qualify as five continental champions might have already books a ticket to Rio de Janeiro.
India's only previous appearance in the women's hockey tournament of the Olympics was in 1980.
India were the dominant side from the beginning against Italy, but failed to make it count. Repeated circle penetrations were of no use as the strikers could not produce a goal-bearing shot in the often crowded circle.
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