A nationwide ceasefire is due to come into effect at midnight on April 10 to bolster the new round of talks between the Saudi-backed Yemeni government and Shiite Huthi rebels.
"With political will, good faith and balance, they could take this opportunity to end the conflict and pave the way towards a permanent and durable end of the war," UN envoy Ismail Ould Cheikh Ahmed said in a statement.
The talks were announced last week after months of shuttle diplomacy by the UN envoy and growing pressure on a Saudi-led coalition to end its air campaign in Yemen.
The envoy said UN teams were working "at full speed" in Sanaa and Riyadh to prepare the delegations and another team was on its way to Kuwait to finalize preparations.
The peace talks are to focus on militia withdrawal, the handover of heavy weapons, security arrangements, the resumption of a dialogue and the creation of a committee on detainees, said the envoy.
Cheikh Ahmed welcomed a prisoner exchange this week that saw nine Saudis swapped for 109 Yemenis, saying the move provides "an important drive to the political process."
The rebels and their allies surrounded a government force that was attempting to recapture the coastal town of Midi and killed 45 loyalist troops on Tuesday and Wednesday, sources said.
At least 15 rebels were also killed in the fighting.
The United Nations has expressed growing alarm over the heavy civilian toll from the airstrikes and the dire humanitarian situation in Yemen, where more than 80 percent of the population is on the brink of famine.
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