The balls, which have a more pronounced seam than the Australian-made Kookaburra, will be used from the second half of next season's competition.
"In recent times Australian teams travelling to England haven't adjusted well to local conditions and the swinging Dukes ball," general manager of team performance Pat Howard said on Wednesday.
"We have been on record saying that we will look at ways to address this deficiency and believe giving players greater experience with the Dukes ball is one way of doing just that.
Australia lost the Ashes series in England last year with former captain Ricky Ponting leading calls for the Dukes ball to be introduced for domestic matches in a bid to help replicate English conditions.
Australia have not won an Ashes campaign in England since 2001, managing just four victories from 20 Ashes Tests during the past four away series.
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