Flipkart had launched the MarQ brand in October last year and currently sells microwave ovens, TVs and washing machines under the brand.
MarQ's 'InnoCool' range of ACs (1 and 1.5 ton variants) will be available on Flipkart from April, while the 32-inch HDR smart TV will go on sale in May.
The ACs and smart TVs were unveiled at the CES, the world's largest consumer technologies show, in the US.
With MarQ, the intent is to offer high quality products that is affordable to everyone, he added.
Menon said the existing products under MarQ have been well-received by customers and he expects the brand to capture 10 per cent volume share in each of the categories.
The MarQ range of products are sold on Flipkart's platform through sellers. These sellers licence the brand from the company, which charges a fee from the sellers.
Flipkart, like its competitor Amazon, has been betting big on private labels to boost its business across categories. Its private labels include the likes of SmartBuy (electronics and other items), Billion (smartphone) and Metronaut (men's wear).
"These ACs and smart TVs will be priced 10-20 per cent cheaper than comparable products. We are also ensuring that customers have access to the best after-sales service (during installation and later)," he said.
Flipkart has partnered LEEL Electronics (India), formerly known as Lloyd Electric and Engineering Ltd, to manufacture the ACs. For televisions, it has an existing tie-up with Dixon Technologies India.
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