Venizelos will first travel to the city of Mariupol on the Sea of Azov near Crimea, where there is a large ethnic-Greek community, and then to Kiev, it said.
"The first thing is to avoid a civil war and avoid a return to the Cold War," said Venizelos, who is also Greece's deputy prime minister and was taking part in a congress of European social-democrats in Rome.
"The second is to organise the situation internally with an inclusive government. Inclusive not just in the political and social sense but also in regional and ethnic terms," he said.
The minister's comments came after Russian President Vladimir Putin won the green light from parliament to send troops into Ukraine after a bloody three-month uprising swept new pro-EU leaders to power while also sparking unrest in the pro-Kremlin Crimean peninsula.
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