One of the world's busiest airports in south-west London, which has now re-opened, suspended arrivals and departures for a temporary period as a result of the incident.
"We can confirm there has been an on-board internal fire involving an Ethiopian Airlines aircraft and the airport's emergency services are in attendance. The aircraft was parked on a remote parking stand. There were no passengers on board and there are no reported injuries at this time," a Heathrow spokesperson said.
The latest incident is yet another involving the Dreamliner aircraft, also part of a set of mega new fleet acquired by Air India.
Fifty Dreamliners worldwide were grounded in January after malfunctions with the plane's lithium-ion batteries.
Boeing later modified the jets with new batteries and flights resumed in April.
The Dreamliner's battery problems followed production difficulties for the aircraft, marketed as a quiet, fuel-efficient aircraft carrying between 201 and 290 passengers on medium-range routes.
"We're aware of the event. We have Boeing personnel on the ground at Heathrow and are working to fully understand and address this," a Boeing spokesperson said.
British Airways is due to take delivery of the first two of its 24 Dreamliners, and Virgin Atlantic is to get the first of its 16 planes in September 2014.
Among the other Dreamliner operators, Ethiopian Airlines Enterprise began flying again in April while Qatar Airways and United Continental Holdings resumed service in May.
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