Dressed in a traditional white wedding dress, bride Louisa Hodkin tied the knot with Alessandro Calcioli, both aged 25, in a Church of Scientology chapel in central London, despite earlier being told the venue was not legally listed as a place of religious worship.
A High Court judge had ruled in 1970 that Scientology services did not count as acts of worship because they involved no "veneration of God or of a supreme being". But the ruling was overturned in December.
Scientology, which counts actors Tom Cruise and John Travolta among its supporters, is recognised as a religion in the US but is treated as a cult in many other countries. It claims a worldwide membership of 12 million people.
Asked how he felt after the wedding, Calcioli told Sky News: "Just ecstatic. A little bit speechless, just so happy that this day has finally come."
He left the chapel arm-in-arm with his new bride as guests applauded and threw confetti.
Britons can marry in a wide range of religious and non-religious venues, but the location must have official approval.
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