Osvaldo Velazquez Garcia, 29, was wounded and detained in a house in the northeastern city of Ciudad Victoria yesterday after a shootout with federal police, said Tamaulipas state prosecutor Ismael Quintanilla.
Velazquez started shooting after he was surrounded, Quintanilla said. He was hit in the right shoulder and lightly wounded in the neck, but he is out of danger.
He was identified as the alleged mastermind of the kidnapping by a 38-year-old accomplice who was arrested late Sunday after Pulido managed to punch one captor and call the police.
The prosecutor said Velazquez was a member of a criminal organisation linked to drug trafficking, kidnappings and extortion.
He did not identify the group, but the Zetas drug cartel is a force in one of the most dangerous regions in Mexico, plagued with homicides, kidnappings and thousands of disappearances.
Velazquez was present at a party that Pulido, a striker with Greek club Olympiakos, attended before he was kidnapped on Saturday, Quintanilla told a news conference.
Pulido, who was part of Mexico's 2014 World Cup team, had left the party with his girlfriend when they were intercepted by four gunmen, who let the woman go.
Authorities say Pulido was freed after he was left alone with one kidnapper in a two-story home and seized on the opportunity to beat up the suspect, take his phone away and call an emergency number.
Police found Pulido within minutes, barely 24 hours after he was kidnapped.
The brothers sat at a table with a dozen friends and siblings of friends. Alan Pulido left with his girlfriend before his brother, and he was kidnapped minutes later.
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