The 50-year-old Gamal Tawfiq was shot in the head by two militants on a motorbike who were following him as he walked from home to work at El-Samran School in the morning in the city of el-Arish.
A security official said the Islamic State's affiliate in Sinai is suspected in the killing.
A school official confirmed Tawfiq's death to The Associated Press but declined to give details. Both officials spoke on condition of anonymity because they were not authorized to speak to reporters.
The Islamic State offshoot in Sinai formerly known as Ansar Beit al-Maqdis has been the most active militant group in the region and has claimed responsibility for most of the attacks that have targeted the police and army forces.
Several Christians were also killed in Sinai last year, including priest Rafael Moussa and health ministry employee Massak Nasrallah whom the militants stopped on his way to el-Arish and asked him about his religion.
The Copts have long complained of discrimination and have been top targets of Islamic militants. Attacks against them increased after the military's ouster of the country's Islamist president, Mohammed Morsi, in 2013.
Christians, along with a large sector of anti-Islamist Egyptians, have supported the army.
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