Deputy Inspector General of Police Sheetal Oraon said the policemen were on patrol duty when a group of Maoists fired indiscriminately on their vehicle killing three of them on the spot.
Two others succumbed to their injuries at separate hospitals.
Three Insas rifles of the police were also taken away by the red rebels from the spot, about 150 km from here, the DIG said.
Director General of Police Rajeev Kumar has reached the spot.
The red rebels have also called a 48-hour bandh in Jharkhand and Bihar from April 6.
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