Captain James' wife Aditi and her sister Anvi accompanied by Congress MP Sanjay Nirupam met the Prime Minister in his Parliament House office.
Captain James of oil tanker MT Ocean Centurian was arrested in July on charges of aiding pirates off the coast of Togo.
"He was arrested for aiding pirates. But the fact is that he gave a tip off to authorities on the presence of pirates," Nirupam told reporters outside Parliament House.
He said Singh has also deputed a Joint Secretary in the PMO, Javed Ashraf, to help manage the captain's release.
Nirupam said he is hopeful that a solution will be found in the next few days.
James' 11-month-old son died of septicaemia in a hospital on December 2. The body of the toddler has been kept at a Mumbai hospital.
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