Nadal, who has not competed since Wimbledon after picking up a right wrist injury, makes his comeback at a tournament he has happy memories of from last year, when he reclaimed the top spot after a previous injury layoff.
The Spaniard returned to number one after dominating 2013's hardcourt events and making the final at Beijing's Olympic Park, a game he lost to Serb Djokovic.
The current world number three has slipped down the rankings due to his absence from competition, and with Djokovic winning four of the last tournaments he entered in Beijing, the 28-year-old knows he will have a battle on his hands to close the gap on his fiercest rival.
"He's always there, semi-finals, finals, winning. He's one of the best players that I have ever seen.
"Normally he likes to play here. We'll see what's going on this year."
Nadal said he felt "fine" following his injury and that his motivation was "high" heading into the tournament.
"I just feel the wrist a little bit when I am starting, when I start to play every day, but then it disappears. I'm in good conditions to compete again," he said.
The second seed in Beijing is 1,505 ATP points behind top seed Djokovic, who has a 19-0 record at the China Open.
The world number 11 is currently chasing points to make November's ATP World Tour Finals in London, which features the top eight men's players.
Nadal faces Richard Gasquet in his opening match and has won all his previous 12 meetings with the French world number 21.
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