Karnataka added 295 runs today to extend their first innings lead to an imposing 484 runs against their struggling opponents.
Nair, who scored his first triple century in first class cricket, piled on 123 runs with K L Rahul in the first session, reaching his 200 just three balls before lunch. Incidentally, this was Nair's first double century.
Batting for two full days, Nair struck 45 fours and a six in his marathon 815 minute knock and reached his 300 with a reverse sweep boundary off Malolan Rangarajan.
Resuming at an overnight score of 323 for 5, the Karnataka batsmen continued where he left off and ensured that there were no casualties till lunch.
Nair took the charge for the holders as he crafted the triple century after resuming on his score of 130. He looked poised for a big score and the intent of Karnataka was clear that they wanted to set a daunting total.
The 23-year old surpassed Gundappa Vishwanath's 247 against Uttar Pradesh in 1977-78, for the highest runs scored by a Karnataka batsman in the Ranji final.
Resuming at a lunch score of 446/5, Karnataka lost K L opener K L Rahul (188) in the seventh over after lunch.
Rahul added 57 runs to his overnight score of 131 before he miscued a shot to be caught at long-on by Vijay Shankar off spinner Malolan Rangarajan.
The 22-year old Rahul hit two sixes off an Aswin Crist over to bring his 150 but missed out on scoring a double.
The duo missed the opportunity to record the highest-ever partnership for sixth wicket in Ranji Trophy by just 31 runs.
Karnataka lost another wicket soon after they posted 500, when Shreyas Gopal (11) was caught behind off Aswin Crist.
Unrelented by the wickets falling at the other end, Nair compiled an unbeaten 117- run stand with skipper Vinay Kumar for the eighth wicket.
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