Samantha Power also said that if confirmed by the Senate, she would try to make the UN more efficient and stand up for freedom.
Her confirmation appeared likely. Several Republicans said Power would be a force in New York even as they pressed the former journalist, human rights campaigner and author to clarify several decade-old comments that the lawmakers suggested were critical of Israel or the United States.
Today she expressed little confidence in the UN authorising any similar intervention in Syria but said Washington could act on its own, if necessary.
"The failure of the UN Security Council to respond to the slaughter in Syria is a disgrace that history will judge harshly," Power told the Senate Foreign Relations Committee.
Moscow and Beijing have blocked US-backed resolutions against the Assad government three times and remain opposed to any effort by Western and Arab countries to force Assad into stepping down.
Russia, however, says it is working with the US to try to get Syria's government and rebels into peace talks.
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