Both companies failed to convince the Committee on Foreign Investment in the United States (CFIUS) to clear the deal, Philips said, adding it is seeking another buyer.
"We will now engage with other parties that have expressed an interest in exploring strategic options for Lumileds," Philips chief executive Frans van Houten said in a statement.
"I am very disappointed about this outcome as this was a very good deal for both Lumileds and the Go Scale Capital-led consortium," Van Houten said.
Lumileds has research and development and production facilities in California's Silicon Valley.
Philips will continue to report the Lumileds business as "discontinued operations", the company added.
Amsterdam-based Philips in October announced that the sale of an 80.1 majority share stake was in doubt because of unspecified CFIUS concerns, but at the time it said they would be addressed.
GO Scale Capital said had the transaction gone through it "would have combined Lumileds' world-leading technology and know-how with the highly competitive LED manufacturing industrial base in China."
"The decision by the CFIUS is a pure piece of trade politics," said Jos Versteeg, analyst at the Amsterdam-based Theodoor Gilissen private bank.
"It's clear that the Americans don't want the technology to go to China," said Versteeg.
"However, the deal will eventually go through, but with another buyer," he told AFP, adding the setback was unlikely to impact on Philips' strategy of moving away from lighting in the healthcare-lifestyle sector.
"It's unlikely though that Philips will get the same price as was offered by GO Scale Capital," he added.
The split is expected to be completed some time this year, with analysts predicting that Philips could eventually sell off Lighting, one of its core businesses for many years.
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