The 63-year-old career diplomat and former rebel-in-exile played a major role in securing Western support for the successful 2011 uprising that toppled the veteran strongman.
Born in 1950 to a business family, Zeidan grew up in the central town of Waddan but then spent half of his life in abroad, mostly in exile.
After obtaining a degree in humanities in 1975, he joined the Libyan diplomatic corps.
In the late 1970s he was sent to work in Libya's embassy in India, alongside the then ambassador Mohamed al-Megaryef, who became president of Libya's ruling national assembly in the post-Gaddafi era.
Still living abroad, Zeidan eventually left the National Front to become a Geneva-based advocate for human rights in Libya.
When the revolt against Gaddafi erupted in February 2011, he played a leading role, along with liberal Mahmud Jibril, in seeking international support for the National Transitional Council, the political wing of the rebellion.
As NTC representative in Europe, Zeidan succeeded in convincing the international community to intervene militarily in support of those battling the Gaddafi regime.
Today, NATO chief Anders Fogh Rasmussen expressed "great concern" after Zeidan was detained, saying the "stability and the rule of law are very important" in Libya as it seeks to rebuild.
Hours later, Zeidan was freed, but it was unclear how.
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