The six were identified as Pradeep, Rathi, Ashok Gehlot, Manjeet Khandewala, Sumit and Satender.
The police also seized six pistols and 23 live rounds from their possession.
A team of Special Cell had arrested Pradeep Solanki, who is wanted in several cases of murder and extortion from west Delhi's Nangloi area on Monday night.
Based on sustained interrogation and information derived from Solanki, police raided a flat in the Bankarwala area and arrested five more gangsters, who had reached there in a White Fortuner.
"On this, three accused ran towards empty fields. While police followed them and asked them to surrender, the accused starting firing upon the police party and fired several rounds, out of which one hit the bulletproof jacket of an assistant sub-inspector. Finally, the accused were arrested," a statement issued by Special Cell of Delhi Police said.
During interrogation, it was found that Manjeet was involved in the killing of former MLA of Najafgarh, Bharat Singh in Najafgarh area here last year and had a reward of Rs 50,000 on him declared by the Delhi Police.
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