The attorney general's office said gunmen were alleged to have opened fire yesterday on an anti-government demonstration in the western city of Valera.
"At that moment, (Edy Alejandro) Teran Aguilar received a bullet in the chest," it said in a statement.
Also wounded in the shootings were an 18-year-old male and a 50-year-old woman, it said. Teran was 23.
The incident came amid massive demonstrations across the country yesterday demanding elections to replace Maduro.
Venezuelan Information Minister Ernesto Villegas charged that opposition protesters in Caracas set fire to a 21-year- old man identified as Orlando Figuera, who he said was being treated at a local hospital for first- and second-degree burns and knife wounds.
"Growing insanity. A human being is set on fire at a 'peaceful demonstration' by the opposition in Caracas," Villegas said on Twitter, posting a video of the incident.
The mayor of a municipality in the eastern part of Caracas said 46 people were injured in yesterday's protests, while in the Caracas suburb of San Antonio Los Altos a youth was wounded by gunfire, the opposition governor of the state of Miranda said.
Seven in 10 Venezuelans reject Maduro's leadership, according to private surveys, amid widespread economic devastation aggravated by the drop in the prices of oil - Venezuela's chief revenue source - in 2014.
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