From 2010 to 2014, the percentage of 15-year-old boys in Europe, Canada and Israel who said they'd smoked their first cigarette at 13 fell from 26 to 22 among boys - but plunged from 22 to 13 for girls.
Alcohol use among young teens in the 42 countries canvassed also went down over the same period, by about 10 per cent.
But when it came to boozing, the percentage of 13-and- under girls who indulged weekly - while still smaller than for boys - did not decline as much, narrowing the gender gap.
"A good start can last a lifetime," she said in a statement.
Conducted every four years, the survey examines self- perception and risky behaviour among 11-, 13- and 15-year olds.
Greenland, Lithuania, Estonia, Latvia and the Czech Republic topped the list of young smokers in 2014, with 38 to 56 per cent of boys, and 36 to 53 per cent of girls, saying they had already lit up by age 13.
In Europe, 16 per cent of all deaths in adults over 30 are due to tobacco - the highest rate of all WHO regions.
Studies have shown that exposure to nicotine during adolescence can have lasting effect on brain development.
Most countries have taken steps to discourage teens from smoking, including banning point-of-sale displays, aggressive public service campaigns, and stiff taxes.
France, Ireland and Britain are also moving toward plain packaging.
Bulgaria tops the list for regular drinking among early teens, with 13 and 20 per cent of 13-year-old girls and boys respectively saying they consume alcohol at least one a week.
When it came to getting flat-out drunk, Denmark topped the ranking of 15-year-olds - nearly 40 per cent - who had been plastered at least twice, with Hungary, Lithuania, Bulgaria and Scotland rounding out the top five.
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