The Kremlin moves came as Russian forces strengthened their control over Crimea, less than a week before the strategic region is to hold a contentious referendum on whether to split off and become part of Russia.
In a televised briefing with President Vladimir Putin, Russian Foreign Minister Sergey Lavrov said proposals made by US Secretary of State John Kerry are "not suitable" because they take "the situation created by the coup as a starting point," referring to the ouster of Ukraine's pro-Kremlin president, Viktor Yanukovych.
Referring to a document he received from Kerry explaining the US view of the situation in Ukraine, Lavrov said: "To be frank, it raises many questions on our side."
"Everything was stated in terms of allegedly having a conflict between Russia and Ukraine, and in terms of accepting the fait accompli," he said.
Lavrov said Kerry delayed a visit to Moscow to discuss the situation, and Russia had decided to prepare new proposals of its own, though he did not say what they were.
"We suggested that he come today ... And we were prepared to receive him. He gave his preliminary consent. He then called me on Saturday and said he would like to postpone it for a while," the minister said.
But in Washington, State Department officials said that it was Russia's refusal to discuss the American proposals that was hurting prospects for a negotiated solution - in particular, the idea of direct talks between Russian officials and those of the new Ukrainian government.
"We are still awaiting a Russian response to the concrete questions that Secretary Kerry sent Foreign Minister Lavrov on Saturday in this regard," State Department spokeswoman Jen Psaki said in a statement.
"Secretary Kerry made clear to Foreign Minister Lavrov that he would welcome further discussions focused on how to de-escalate the crisis in Ukraine if and when we see concrete evidence that Russia is prepared to engage on these proposals," she said.
The statement said Kerry, in weekend discussions with Lavrov, reiterated Washington's demand that Moscow pull back its troops from Ukraine and end attempts to annex the Crimean peninsula. Kerry also called on Russia to cease what the statement described as "provocative steps" to allow diplomatic talks to continue.
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