President Bashar al-Assad's forces have seized two-thirds of the former rebel bastion in east Aleppo since they began an operation to recapture all of Syria's battered second city in mid-November.
The rapid gains for regime forces have left opposition fighters reeling and on Monday Russian Foreign Minister Sergei Lavrov said talks would be held with Washington on a complete rebel evacuation from the city.
"During the Russian-American consultations the concrete route and timeframe for the withdrawal of all fighters from eastern Aleppo will be agreed upon," Lavrov said, adding that the discussions in Geneva would likely start on Tuesday or Wednesday.
The loss of Aleppo would mark the biggest defeat yet for opposition forces in Syria's five-year civil war.
The assault has raised an international outcry and the UN Security Council was due to vote later Wednesday on a draft resolution for a seven-day ceasefire in the city.
But Lavrov appeared to torpedo that move, suggesting Moscow might use its veto to block the resolution.
"The draft resolution... Is, for the most part, a provocative step that undermines Russian-American efforts," he told a press conference.
It says it is not involved in the current offensive in Aleppo, which has seen the army advance quickly as it pounds the east with air strikes, barrel bombs and artillery fire.
Overnight, the army and allied forces seized the Qadi Askar neighbourhood and effectively encircled the large Shaar district, the Syrian Observatory for Human Rights monitor said.
Observatory director Rami Abdel Rahman said the army was attacking both from inside east Aleppo and from government-held western districts.
"The regime is draining the rebel fighters of ammunition by opening many fronts at the same time," he said.
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