England prevailed through a 69th-minute penalty corner rebound conversion by Simon Mantell.
India had an equal run of play against England, and even saw a penalty stroke being cancelled, paving the way for England's victory.
Ashley Jackson's penalty corner shot was blocked by goalkeeper P.R. Sreejesh, but Mantell capitalised on the rebound by sending a diagonal reverse shot into the net to leave the Indian players crestfallen in the dying moments of the game.
England opened the scoring in the 26th minute through Mark Gleghorne's penalty corner conversion, and India equalised through Dharamvir Singh in the 30th minute.
Australia, who today defeated Spain 3-0, are at the top of the Group A table with six points from two successive wins against Malaysia and Spain.
After being held to a 1-1 draw in their first game by Spain, England now have four points from two matches.
India had the run of play at the start and forced their first penalty corner in the 11th minute, when the ball was carried by a England defender inside the circle. The foul was not noticed by the umpire, but India made a referral and the foul was confirmed. It led to penalty corners being awarded two more times before India wasted the opportunity as the push was not stopped properly and Manpreet's attempt to continue the attack saw the ball soar over the cross-bar.
At the other end, Indian goalkeeper Sreejesh padded away a shot from Dan Fox. India then came close to scoring in the 23rd minute on another Dharamvir cross to Mandeep Singh, but he sent the cross high in haste.
An unnecessary obstruction on the 25-yard line by Yuvraj Walmiki gave England their first penalty corner, which was converted by Mark Gleghorne with a rising shot.
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