Moss, 39, will grace the magazine's 60th anniversary issue, which will be published in December, reported Digital Spy.
"She's (Kate) a worldwide celebrity, is iconic, and crosses the boundaries from sexual imagery to upscale modelling. It's a natural for us," Hefner said.
Reports about Moss would pose for Playboy emerged in June when her hairdresser accidentally revealed that he had worked on the shoot.
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