"NATO Secretary General, Mr Jens Stoltenberg, will travel to Lviv and Kiev on Monday 21 and Tuesday 22 September 2015," a statement said, indicating he would hold talks with President Petro Poroshenko.
Ukraine, where around 7,000 people have been killed in fighting since April 2014, is a key partner but not a member of the 28-nation military alliance.
He will also hold talks with Prime Minister Arseniy Yatsenyuk and the parliamentary speaker, and will attend a meeting of Ukraine's National Security and Defence Council, it said.
Russia denies any direct role in a conflict which has plunged East-West relations into a deep freeze reminiscent of the Cold War.
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