The Palestinian delegation, which included the Palestinian Authority's spy chief Majid Faraj, will be joined by Hamas representatives and meet Egyptian officials on Sunday.
US Middle East envoy Frank Lowenstein was also expected to arrive in Egypt's capital for talks on ending the 26-day conflict in Gaza, which has so far claimed more than 1,670 Palestinian lives and displaced up to a quarter of the territory's population.
Israel had been invited to send a delegation, but a senior political official quoted by army radio accused Gaza's Hamas rulers of not being "interested in an arrangement" after a temporary ceasefire broke down on Friday.
The Palestinian delegation will discuss their demands with Egyptian mediators on Sunday, including a call for the end of an eight-year blockade of Gaza and the release of Palestinian prisoners.
Israel called off its participation after accusing Hamas of abducting one of its soldiers on Friday after a 72-hour ceasefire went into effect.
Hamas denied knowledge of the soldier's whereabouts. And suggested he had perhaps been captured in fighting and then killed in subsequent Israel bombardment alongside Palestinian militants.
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