After yesterday's five-hour talks billed as "difficult", focus shifted to the conflict in Syria, with host Chancellor Angela Merkel and French President Francois Hollande pressing Russian President Vladimir Putin over Moscow's involvement in the civil war.
Ukrainian Petro Poroshenko said the four signatories of the frayed 2014 Minsk peace accords had managed to make tentative progress after months of impasse.
"Between now and the end of November we have to approve a roadmap. It will be a document on the implementation of all the Minsk accords," he said in a press conference after the Berlin summit, according to Russian news agencies.
"Things are stalled in many areas such as the ceasefire, political issues and humanitarian issues," she told reporters Tuesday.
"We have to seize every chance we have for progress. I have to say that we cannot expect a miracle but it is worth every effort at this point."
Ahead of the meeting, Moscow had poured cold water on hopes for headway toward a lasting resolution to the Ukraine conflict.
"We do not expect any breakthroughs," Kremlin spokesman Dmitry Peskov told reporters ahead of Putin's trip.
Russia backs a separatist, pro-Moscow insurgency in eastern Ukraine that has claimed nearly 10,000 lives.
But it denies accusations that it has sent troops and weapons across its border with Ukraine to fuel the conflict.
Beyond Ukraine, Moscow was also under fire over its involvement in the Syrian civil war at the Berlin talks.
Speaking of the "disastrous" situation in the besieged Syrian city of Aleppo, Merkel said she and Hollande would talk to Putin "about somehow alleviating people's suffering".
The European leaders will issue a condemnation against Russia over attacks on civilians in Syria's Aleppo, urge an end to fighting and call for a revived political process, according to a draft statement seen by AFP.
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