"To be able to fully exercise my right to defense, which has up until now been violated, I resign with immediate effect my duties as chairman of the Brazilian Olympic Committee," Carlos Nuzman said in a statement released Saturday but dated Friday.
He also resigned as chairman of the Rio 2016 organizing committee, which ran the first Olympics ever held in South America.
The Games were generally lauded as a success at the time. However, the aftermath has produced a flow of corruption scandals alleging the embezzlement of millions of dollars.
Brazilian officials said last month Nuzman was the "lynchpin" in a plot to get the IOC to pick Rio. Former Rio state governor Sergio Cabral, who is serving a 14-year prison term for bribery and money laundering, allegedly masterminded the plot.
On Friday, the IOC provisionally suspended Nuzman, stripping him of his honorary membership and removing him from the coordination committee for the 2020 Tokyo Olympics.
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