"We are starting officially the Geneva talks... The discussions are starting," Staffan de Mistura told reporters.
"We will meet the government tomorrow (Tuesday) and will invite the HNC (High Negotiations Committee) tomorrow afternoon to go deeper into the issues raised."
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He addressed reporters after wrapping up a preliminary meeting with the HNC, which arrived in Geneva yesterday after days of deliberating whether they would attend.
"The first immediate objective is to make sure the talks continue and that everyone is on board," de Mistura said.
He could not comment on how long he expected the first round of talks to last, but said he hoped negotiations "achieve something" by February 11.
The devastating war in Syria has ravaged the country for nearly five years, killing more than 260,000 people and forcing millions to flee their homes.
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