Guterres has made gender parity a priority of his tenure which begins on January 1.
Senior Brazilian foreign ministry official, Maria Luiza Ribeiro Viotti, will serve as Guterres' chief of staff while Kyung-wha Kang of South Korea was appointed to the new position of special advisor on policy.
Mohammed was widely tipped to become UN deputy secretary-general after she led the UN's successful negotiations on the new sustainable development goals.
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