De Mistura had planned to meet with a government delegation today morning before meeting with the opposition, but the earlier meeting was postponed, his spokeswoman Khawla Mattar said.
The envoy had officially met with the government delegation on Friday but only paid a courtesy visit to the opposition yesterday. Mattar said the today morning meeting would be rescheduled because de Mistura wanted to hold an official meeting with the opposition before launching the indirect talks.
De Mistura has decided that these will be "proximity talks," rather than face-to-face sessions, meaning that he plans to keep the delegations in separate rooms and shuttle between them. He has tamped down expectations by saying he expects talks to last for six months.
Earlier in the day, de Mistura's office said his meeting with the government delegation planned for today morning has been rescheduled.
The opposition delegation, known as the High Negotiations Committee, or HNC, said it will meet de Mistura in his office Monday afternoon after receiving reassurances from several countries as well as the UN envoy regarding sieges on rebel-held areas and bombardment of civilians.
"We have come to Geneva to seek relief for our people by insisting UN Security Council resolution 2254 is implemented, which means humanitarian relief, the lifting of sieges, and the end of attacks on civilians," spokesman Salem al-Mislet said in a statement.
The talks in Geneva are part of a process outlined in last month's UN resolution that envisions an 18-month timetable for a political transition in Syria, including the drafting of a new constitution and elections.
She was referring to a besieged suburb of the capital Damascus that opposition activists say was subjected to intense bombardment yesterday.
The UN human rights chief, Zeid Raad al-Hussein, meanwhile told reporters in Geneva he hopes that peace talks "will lead to the end of all these horrific abuses - human rights abuses and violations of international humanitarian law - that we are all too familiar with.
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