The deal, signed at the Farnborough Airshow in London, is worth $13.8 billion at the catalog price but airlines usually get a discount for bulk purchases.
Malaysian-based AirAsia X said in a statement late Tuesday that deliveries will take place between 2018 and 2024.
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The AirAsia group is one of Airbus's largest airline customers in the world, with 536 Airbus aircraft, excluding the new deal.
AirAsia X, launched in late 2007, flies to 14 destinations in Asia, Australia and the Middle East.
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