The chief UN mediator expressed frustration over inflammatory public remarks by the two sides as he sought to identify some less-contentious issues in hopes of achieving any progress at all at the bargaining table.
But even the most modest attempts at confidence-building measures faltered including humanitarian aid convoys to besieged parts of the central city of Homs and the release of detainees.
Veteran mediator Lakhdar Brahimi sombrely declared at the end of the day that he had little to report.
The gulf between the two sides was on full display at a turbulent morning session in which the delegations from the opposition and the Syrian government faced off on the question of Assad's future.
The Western-backed Syrian National Coalition wants an interim replacement for Assad, reiterating at every opportunity that the stated goal of the peace conference, agreed upon by international powers in preliminary talks in June, is to establish a transitional government with full executive powers.
"We came here with the intention of discussing a transitional governing body and they came with the intention of consecrating Bashar Assad's presence," said Rima Fleihan, a member of the coalition's negotiating team.
Murhaf Jouejati of the coalition said the meeting ended on a "sour note," and the session was broken up by Brahimi after the government delegation became confrontational. "We thought there was no point in continuing this since it was going to be a dialogue of the deaf," Jouejati said.
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